Question 102 - (a) As an approximation, let v = Zc / 137 where v is the radial velocity for 1 s electron of an element, c is the speed of light, Z is the atomic number. For gold with Z = 79, find the radial velocity of its 1 s electron, in term of c and percentage of the speed of light. (b) As an approximation, let A x A = 1 - Z x Z / 18769 where A is the ratio of the relativistic and non-relativistic Bohr radius. Find the value of A.
Answer 102 - (a) Approximately v = Zc / 137 = (79 / 137) c = 0.5766 c or 57.66 % of the speed of light. (b) Approximately A x A = 1 - Z x Z / 18769 = 1 - 79 x 79 / 18769 = 0.667 then A = 0.817. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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ACCOUNTING AND FINANCIAL ENGINEERING - EXAMPLE 34.19 : In the purchase of a unit of engineering office, a loan has been made to a bank with the following details : Term N = 30 years; interest rate R = 8.07 % / year; security : primary residence; present value pv = $450000; salary = $75000 / year or $56000 / year after tax. (a) Let the discounted present value PV = [ 1 - 1 / (1 + r) ^ n ] / r for arrears, where r = interest rate of discount, n = number of payment, ^ = symbol for power. If the loan repayment was made monthly : (i) calculate the value of r where r = R / k and R is in decimal value; (ii) find the value of n where n = kN; (iii) estimate the value of k where k = number of repayment per year; (iv) calculate the value of PV based on the formula of discounted present value. (b) Calculate the monthly repayment of the loan, MR based on the following formula : pv = PV x MR. (c) Find the percentage of salary remains after paying the loan every month.
Question 50 - An aqueous solution with 2.5 g of a protein dissolved in 600 cubic centimeters of a solution at 20 degree Celsius was placed in a container that has a water-permeable membrane. Water permeated through the membrane until the h - level of the solution was 0.9 cm above the pure water. (a) Calculate the absolute temperature of the solution, T in Kelvin, where T (Kelvin) = T (degree Celsius) + 273.15. (b) Calculate the osmotic pressure, P of the solution by using the formula P = hrg where h is level of the solution, r is density of water with 1000 kg per cubic meter, g = 9.81 N / kg as gravitational acceleration. (c) Calculate the concentration of the protein solution, C in kg / cubic meter. (d) Calculate the molecular weight of the protein, (MW) = CRT / P where R = 8.314 Pa cubic meter / (mol K) as ideal gas constant.
QUANTUM BIOLOGY - EXAMPLE 33.10 : The wavefunction starts out in a superposition of possible states in a closed black box like this : Ψ (kitty) = 0.7071 Ψ (alive) + 0.7071 Ψ (dead) where Ψ (kitty) = wavefunction of a kitten, Ψ (alive) = wavefunction of a living kitten, Ψ (dead) = wavefunction of a dead kitten. By prediction and calculation, find the probability of : (a) a living kitten inside the black box; (b) a dead kitten inside the black box.
ENGINEERING NUMERICAL METHODS - EXAMPLE 19.3 : There are 2 simultaneous equations : (A1) x + (B1) y = D1 and (A2) x + (B2) y = D2. (a) By using Excel program, find the values of x and y when A1 = 80, A2 = 150, B1 = 52, B2 = 100, D1 = 3.5 and D2 = 2.3. (b) Write the expression of Excel in the form of =MMULT(MINVERSE(W:X),Y:Z) in order to get the values of x and y. W, X, Y and Z may be A1, A2, B1, B2, D1 and D2.
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Question 75 - The molecular weights M in kg / mol of 3 different monomers a, b and c in a polymer are Ma = 14, Mb = 16 and Mc = 18. The fraction of polymer chain X of 3 different monomers a, b and c in a polymer are Xa = 0.5, Xb = 0.3 and Xc = 0.2. (i) Calculate number average molecular weight by using the formula Ma Xa + Mb Xb + Mc Xc. (ii) Calculate weight average molecular weight by using the formula (Ma Xa Ma + Mb Xb Mb + Mc Xc Mc) / (Ma Xa + Mb Xb + Mc Xc). (iii) Calculate the polydispersity by using the answer in (ii) divided by answer in (i). (iv) If the molecular weight of repeat unit is 12, calculate the degree of polymerization by using the formula (Ma Xa + Mb Xb + Mc Xc) / (molecular weight of repeat unit).
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