QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.10 : There are 6 spin orbitals in p subshell in a ground state carbon atom. Only 2 electrons fill the p subshell. Number of different ways for n electrons to occupy the k spin orbitals are k! / [ (n!) (k-n)! ]. Find the number of different configurations of electrons to occupy the p subshell in a carbon atom.
QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - ANSWER 31.10 : Let k = 6, n = 2. Number of ways = k! / [ (n!) (k-n)! ] = 6! / [ (2!) (6-2)! ] = 6! / (2! 4!) = 15. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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Question 81 - (a) In natural gas pipe sizing, the length of the pipe from the gas source metre to the farthest appliances is 60 feet. The maximum capacities for typical metallic pipes of 60 feet in length are : 66 cubic feet per hour for pipe size of 0.5 inches; 138 cubic feet per hour for pipe size of 0.75 inches; 260 cubic feet per hour for pipe size of 1 inch. By using the longest run method : (i) Find the best pipe size needed for the capacity of 75 cubic feet per hour. (ii) Estimate the suitable range of capacities for the pipe size of 1 inch. (b) The maximum capacities for typical metallic pipes of 50 feet in length are : 73 cubic feet per hour for pipe size of 0.5 inches; 151 cubic feet per hour for pipe size of 0.75 inches; 285 cubic feet per hour for pipe size of 1 inch. By using the branch method find the best pipe size needed for the capacity of 75 cubic feet per hour when the length of the pipe from the gas source metre to the appliance is 52 feet.
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Question 59 – There are 5 simultaneous equations with 5 unknowns as follow : 16 V – 4 X – Z = 36, 4 X – 4 W – Y + Z = 3, 8 V + 4 W – X + Y = 10, X – W = 1, V + W = 0. Find the values of V, W, X, Y and Z accurately within 15 minutes. State the computer program that you use to get the answers.
QUANTUM COMPUTING - EXAMPLE 32.6 : (a) Let H | 0 > = 0.707 ( | 0 > + | 1 > ), H | 1 > = 0.707 ( | 0 > - | 1 > ). Find the values for H | 0 > + H | 1 > and H | 0 > - H | 1 >. (b) In quantum computing, a qubyte is a quantum byte, or 8 quantum bits, a sequence processed as a unit. A qubit is a quantum bit. According to Alexander Holevo in his theorem, n qubits cannot carry more than n classical bits of information. What is the maximum amount of classical bits of information that can be carried by 1 qubyte.
QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.9 : When an algebraic product is defined on the space, the Lie bracket is the commutator [x,y] = xy - yx according to Lie algebra in mathematics. If [p,x] f(x) = px f(x) - xp f(x), p = -ih d / dx, find the value of [p,x] in term of i and h.
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In a furnace, 2 chemical reactions are happening – 1 mole of solid carbon reacts with 1 mole of oxygen gas to generate 1 mole of carbon dioxide gas; 1 mole of solid carbon reacts with 0.5 mole of oxygen gas to generate 1 mole of carbon monoxide gas. In a given process, 100 kmol of carbon is burned in a furnace. (a) Calculate the theoretical oxygen gas needed by assuming that all the carbon is burned completely to carbon dioxide gas. (b) Calculate the theoretical air needed by assuming that all the carbon is burned completely to carbon dioxide gas and there is only 21 % of oxygen gas. (c) Determine the amount of air required (in kmol) if 50 % excess oxygen gas must be satisfied for (a) and (b). (d) It has latter been found that 20 % of the carbon undergoes incomplete combustion resulting to carbon monoxide gas production. The rest of the carbon undergoes complete combustion. Calculate the total oxygen gas required stoichiometrically based on the actual process.
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QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.5 : In a wavefunction, let P(x) = A cos kx + B sin kx. By using the boundary conditions of x = 0 and x = l, where P(0) = P(l) = 0, prove by mathematical calculation that P(x) = B sin (npx / l) where p = 22 / 7 approximately, n is a rounded number. A, B and k are constants.
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