QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.9 : When an algebraic product is defined on the space, the Lie bracket is the commutator [x,y] = xy - yx according to Lie algebra in mathematics. If [p,x] f(x) = px f(x) - xp f(x), p = -ih d / dx, find the value of [p,x] in term of i and h.
QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - ANSWER 31.9 : Let [p,x] f(x) = px f(x) - xp f(x) = (-ih d / dx) x f(x) - x (-ih d / dx) f(x) = -ih { d / dx [ x f(x) ] - x d f(x) / dx } = -ih [ f(x) ] + x d f(x) / dx - x d f(x) / dx = -ih [ f(x) ]. Then [p,x] = -ih. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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THERMODYNAMIC - EXAMPLE 10.3 : According to Raoult's law, the pressure when vapor is completely condensed, P = x(1) P(1) + x(2) P(2) ... + x(n) P(n) when x(1), x(2) ... x(n) are the mole fractions of component 1, 2 ... n and P(1), P(2) ... P(n) are the vapor pressures of component 1, 2 ... n. A vapor at 74 degree Celsius containing 70 mole % water and 30 mole % ethanol is to be completely condensed. At the temperature of 74 degree Celsius vapor pressure is 0.38 atm for water and 0.97 atm for ethanol. What is the minimum pressure the compressor must be operated?
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GENETIC ENGINEERING - EXAMPLE 27.4 : According to Hardy-Weinberg Equation, p x p + 2 x p x q + q x q = 1 where p = dominant allele frequency and q = recessive allele frequency. Let p + q = 1. Fraction of population has 2 copies of the p gene = p x p. Fraction of population has 2 copies of the q gene = q x q. Fraction of population has a copy of p gene and a copy of q gene = 2 x p x q. In a small town, the allele frequency is q = 0.2 for a recessive gene, the delta-32 mutation, that gives human protection from HIV infection. (a) Find the allele frequency of a dominant gene, p. (b) What percent of the population has at least a copy of the gene that cause the population either immune to HIV or less susceptible to the disease?
Question 80 - Liquid octane has a density of 703 kilograms per cubic metre and molar mass of 114.23 grams per mole. Its specific heat capacity is 255.68 J / (mol K). (a) Find the energy in J needed to increase the temperature of 1 cubic metre of octane for 1 Kelvin. (b) At 20 degree Celsius, the solubility of liquid octane in water is 0.007 mg / L as stated in a handbook. For a mixture of 1 L of liquid octane and 1 L of water, prove by calculations that liquid octane is almost insoluble in water.
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BIOCHEMICAL ENGINEERING INSTRUMENTATION - EXAMPLE 29.1 : In the application of Theory of Spectrometry in spectrophotometer, let n = N x C x V, V = A x t, e = a x N where n = number of molecules, N = Avogadro's number, V = volume of cuvette, A = area of cuvette, t = thickness of cuvette, C = concentration of fluid in the cuvette, e = extinction coefficient, a = effective area of molecule. (a) By using calculus in dI = -I x a x N x C x dt, prove that ln (I / Io) = -a x N x C x t, where dI is the small difference in I and dt is the small difference in t. I = intensity of light. Io = initial intensity of light. (b) Show by calculations that ln (Io / I) = e x C x t based on the answer in the previous question (a). (c) Find the equation of log (Io / I) as a function of e, C and t based on the answer in the previous question (b).
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