ENGINEERING NUMERICAL METHODS - EXAMPLE 19.2 : For a mixture of benzene (B), toluene (T) and xylene (X), the equation applies where x for B, T and X will sum up to 1. The equation of x for each component is x = (L / V + 1) (F) / (L / V + K). The data of F for each component are : 0.5 for B, 0.35 for T, 0.15 for X. The data of K for each component are : 1.98 for B, 0.76 for T, 0.24 for X. When x for B + x for T + x for X = 1, find the values of (a) L / V; (b) x for each component of B, T, X respectively. You may use Excel program - Data : What-If-Analysis for Goal Seek to perform the iterative calculations.
ENGINEERING NUMERICAL METHODS - ANSWER 19.2 : By using Excel program, L / V = 0.654. The data of x are : 0.31 for B, 0.41 for T, 0.28 for X. You may bring your own calculator on laptop or phone with Excel program to assist the trial and error. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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REACTION ENGINEERING - EXAMPLE 13.3 : The half-life for first order reaction could be described in the differential equation dC / dt = -kC where k is a constant, C is concentration and t is time. (a) Find the equation of C as a function of t. (b) Find the half life for such reaction or the time required to reduce 50 % of the initial concentration, where k = 0.139 per minute. (c) When the initial concentration Co is 16 mol / cubic metre, how long does the reaction required to achieve the final concentration of 1 mol / cubic metre?
REACTION ENGINEERING - EXAMPLE 13.2 : A batch reactor is designed for the system of the irreversible, elementary liquid-phase hydration of butylene oxide that produces butylene glycol. At the reaction temperature T = 323 K, the reaction rate constant is k = 0.00083 L / (mol - min). The initial concentration of butylene oxide is 0.25 mol / L = Ca. The reaction is conducted using water as the solvent, so that water is in large excess. (a) Let the molecular weight of water is 18 g / mol and the mass of 1 kg in 1 L of water, calculate the molar density of water, Cb in the unit of mol / L. (b) Determine the final conversion, X of butylene oxide in the batch reactor after t = 45 min of reaction time. Use the formula X = 1 - 1 / exp [ kt (Cb) ] derived from material balance. (c) Find the equation of t as a function of X.
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