QUANTUM BIOLOGY - EXAMPLE 33.2 : (a) In a biomolecule, ATP hydrolysis will produce 3 kcal / mol to 60 kcal / mol of energy, according to energy scale. Find the range of such energy generation if 2 moles of molecules involved. (b) A formula is given by ln P = ln a + b ln W where P = metabolic rate, W = body size, a = dependent of taxa, b = scaling exponent. If b is approximately 1 for plant, and b is approximately 0.75 for animal, find the relationship of P as a function of a and W in plant.
QUANTUM BIOLOGY - ANSWER 33.2 : (a) Range of energy, E = 3 kcal / mol to 60 kcal / mol. For 2 moles, multiply the range by 2 so that E = (3 x 2) to (60 x 2) kcal or E = 6 kcal to 120 kcal. (b) Let ln P = 1n a + b ln W. For plant, b = 1 approximately. Then ln P = 1n a + ln W = ln (aW), P = aW. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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Question 75 - The molecular weights M in kg / mol of 3 different monomers a, b and c in a polymer are Ma = 14, Mb = 16 and Mc = 18. The fraction of polymer chain X of 3 different monomers a, b and c in a polymer are Xa = 0.5, Xb = 0.3 and Xc = 0.2. (i) Calculate number average molecular weight by using the formula Ma Xa + Mb Xb + Mc Xc. (ii) Calculate weight average molecular weight by using the formula (Ma Xa Ma + Mb Xb Mb + Mc Xc Mc) / (Ma Xa + Mb Xb + Mc Xc). (iii) Calculate the polydispersity by using the answer in (ii) divided by answer in (i). (iv) If the molecular weight of repeat unit is 12, calculate the degree of polymerization by using the formula (Ma Xa + Mb Xb + Mc Xc) / (molecular weight of repeat unit).
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ACCOUNTING AND FINANCIAL ENGINEERING - EXAMPLE 34.2 : (a) In the pricing of a coupon bond, the formula is : P = c / (1 + r) + (c + B) / [ (1 + r) (1 + r) ] for 2 years to maturity, where c = annual coupon payment (in dollars, not a percent), B = par value, P = purchase price. Five years ago someone bought a 20 year coupon bond and would like to get rid of it now : A coupon rate of 7 %, it matures in exactly 2 years, par value is $1000, current interest rate is 5 %. (i) Find the value of c. (ii) Find the value of r or interest rate. (iii) Find the value of P. (iv) Guess the formula for P when the maturity period is 3 years, if such formula for 1 year duration is P = (c + B) / (1 + r). (b) In lemma of Ito on a Forward, recall that a forward contract is priced at : ln F = ln S + rT. Find the value of F in 5 decimal points when S = $100, r = interest rate = 0.05 / year, T = duration = 1 year.
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MASS TRANSFER - EXAMPLE 4.3 : According to Adolf Eugen Fick (1829 - 1901) : rate of diffusion v increases with less wall thickness t, increased area A and decreased molecular weight of a fluid M. The diffusion constant D decreased with increasing M. (a) By assuming v, t, dP, A, M and D changes proportionally of each other, find the equation of v as a function of t, dP, A and D. (b) The ratio of self diffusion constant D, at T = 273 K and P = 0.1 MPa, for gases B and C are 1.604 : 0.155. If only 2 gases exist in such a system : hydrogen and nitrogen, find the type of gas for B and C with reference to their molecular weights M. (c) By using the equation of kinetic energy 0.5 MV = constant where V = square of v, find the ratio of V for B and V for C, or V(B) / V(C), as a function of M(B) and M(C), where M(B) is molecular weight of B and M(C) the molecular weight of C : Graham's Law of Diffusion.
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