QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.3 : In photoelectrical effect analysis of quantum chemistry, let E = kinetic energy of electron, p = intensity of UV light, f = frequency of UV light. According to Classical Theory, E = c for all values of f, E = mp. According to Quantum Theory, E = c for all values of p, E = mf + c. In a graph, m and c are constants where m is slope and c is y intercept. If m = 2 and c = 3 with similar value of E : (a) find the value of p according to Classical Theory; (b) find the value of f according to Quantum Theory.
QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - ANSWER 31.3 : (a) E = c = 3, then E = mp = 2p = 3, then p = 3 / 2. (b) E = c = 3, then E = mf + c = 2f + 3 = 3, then f = (3 - 3) / 2 = 0. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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Question 107 - In N + 1 Rule in Quantum Chemistry, whenever a spin 1 / 2 nucleus is adjacent to N other nuclei, it is split into N + 1 distinct peaks. In 1 peak or singlet, there is only 1 magnitude. In 2 peaks or doublet, the ratio of magnitude of each peak is 1 : 1. In 3 peaks or triplet, the ratio of magnitude of each peak is 1 : 2 : 1. In 4 peaks or quartet, the ratio of magnitude of each peak is 1 : 3 : 3 : 1. In 5 peaks or quintet, the ratio of magnitude of each peak is 1 : 4 : 6 : 4 : 1. (a) By using binomial coefficients or Triangle of Pascal find the ratio of magnitude of each peak if 6 peaks exists. (b) How many adjacent nuclei are available in a spin 1 / 2 nucleus in such situation of 6 peaks?
Question 66 – The drag coefficient Cd = 0.05 and lift coefficient Cl = 0.4 for a levelled flow aircraft are measured. The velocity of the aircraft is v = 150 ft / s with its weight W = 2677.5 pound-force. (a) Find the value of the lift of the aircraft, L, when it is also its weight. (b) The drag of the aircraft, D = Cd M, L = Cl M. Find the value of D. (c) The power required is P = Dv. If 1 pound-force x (ft / s) = 1.356 W, find the value of P in the unit of Watt or W.
all subject of chemical engg
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QUANTUM COMPUTING - EXAMPLE 32.8 : In quantum computing, a quantum state is given by S = a | 00 > + b | 01 > + g | 10 > + d | 11 >. (a) Find S in term of | 0 > and | 1 > etc. (b) The probability of getting x is P(x). For S = 0.5 | 00 > + 0.5 | 01 > + 0.5 | 10 > + 0.5 | 11 >, find P(0) and P(1). Hint : P(00) + P(01) = P(0) = a x a + b x b, P(10) + P(11) = P(1) = g x g + d x d.
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