i need last year question paper of GATE exam of chemical
stream.but i failed i geting exam papers.soits humble
request to u that if any body found last years GATE exam
paper of chemical stream then send it to on this mail
address.i shall be thankful to u for this.
mail address:- sachin_4255@yahoo.co.in
thank you.
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Explain what are the advantages of using gear pumps?
BIOCHEMICAL ENGINEERING INSTRUMENTATION - EXAMPLE 29.4 : The resolution of separation, Rs for chromatography is given by the formula Rs = (difference in retention time) / (average width at the base). In a chromatogram, 3 peaks a, b and c are found. Average widths W at the bases of the solutes are : Wa = 20 s, Wb = 40 s, Wc = 30 s. Resolutions of separation, Rs for solutes b and c in comparison to a are 2 and 4 respectively. The differences in retention times T for b and c in comparison to a are (Tb - Ta) and (Tc - Ta), Ta = Tc - Tb : (a) Form 2 equations involving Rs as a function of Wa, Wb, Wc, Ta, Tb and Tc. (b) Find the values of Ta, Tb and Tc.
Question 107 - In N + 1 Rule in Quantum Chemistry, whenever a spin 1 / 2 nucleus is adjacent to N other nuclei, it is split into N + 1 distinct peaks. In 1 peak or singlet, there is only 1 magnitude. In 2 peaks or doublet, the ratio of magnitude of each peak is 1 : 1. In 3 peaks or triplet, the ratio of magnitude of each peak is 1 : 2 : 1. In 4 peaks or quartet, the ratio of magnitude of each peak is 1 : 3 : 3 : 1. In 5 peaks or quintet, the ratio of magnitude of each peak is 1 : 4 : 6 : 4 : 1. (a) By using binomial coefficients or Triangle of Pascal find the ratio of magnitude of each peak if 6 peaks exists. (b) How many adjacent nuclei are available in a spin 1 / 2 nucleus in such situation of 6 peaks?
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Question 103 - (a) Let | - > = 1 | x > + 0 | y >, | | > = 0 | x > + 1 | y >. Find the value of 2 | x > + 3 | y > in term of | - > and | | >. (b) Let m to be the reduced mass. Find the value of m in term of Ma and Mb where 1 / m = 1 / Ma + 1 / Mb.
QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.5 : In a wavefunction, let P(x) = A cos kx + B sin kx. By using the boundary conditions of x = 0 and x = l, where P(0) = P(l) = 0, prove by mathematical calculation that P(x) = B sin (npx / l) where p = 22 / 7 approximately, n is a rounded number. A, B and k are constants.
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Question 77 - The molecular weights M in kg / mol of 3 different monomers a, b and c in a polymer are Ma = 14, Mb = 16 and Mc = 18, with their respective quantities in N units having the ratio of Na : Nb : Nc = 2 : 3 : 5. (a) Find the numerical average molecular weight of the polymer by using the formula (Ma Na + Mb Nb + Mc Nc) / (Na + Nb + Nc). (b) Find the weighted average molecular weight of the polymer by using the formula (Ma Na Ma + Mb Nb Mb + Mc Nc Mc) / (Ma Na + Mb Nb + Mc Nc). (c) Calculate the polydispersity Q by using the answer in (b) divided by answer in (a). (d) Find the volumetric average molecular weight of the polymer by using the formula (Ma Na Ma Ma + Mb Nb Mb Mb + Mc Nc Mc Mc) / (Ma Na Ma + Mb Nb Mb + Mc Nc Mc). (e) Estimate the polydispersity Q by using the answer in (d) divided by answer in (b).