BIOCHEMICAL ENGINEERING INSTRUMENTATION - EXAMPLE 29.6 : In infrared spectrum, one of the factors affecting peak location is the mass of the atoms. The stretching frequency of a bond connected to a lighter atom will be greater than the same bond connected to a heavier atom. (a) For halogens like florine (F), chlorine (Cl), bromine (Br), iodine (I) and astatine (At), what is their IUPAC group number? Hint : The proton numbers for F, Cl, Br, I and At are 9, 17, 35, 53 and 85 respectively. (b) For the compounds of H-F, H-Cl, H-Br, H-I and H-At, which one has the lowest stretching frequency and which one has the highest stretching frequency? State the reasons.
BIOCHEMICAL ENGINEERING INSTRUMENTATION - ANSWER 29.6 : (a) 17. (b) Lowest stretching frequency : H-At. Highest stretching frequency : H-F. Reasons : F has the lowest proton number 9 and At has the highest proton number 85. For the compound of H-X, the stretching frequency of the bond decreases when the mass of X increases and vice versa. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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Question 85 - (a) Three genes, I, J and K are available. All these genes are linked with respect to one another. If the percent recombination between I and J is 8 %, that between J and K is 10 %, and that between K and I is 18 %, what is the order of the gene? (b) Twenty six genes, a, b, c, d, e, f, ... x, y and z are available. All these genes are linked with respect to one another. If the percent recombination between a and b is 3 %, between b and c is 3 %, between c and d is 3 %, ... between w and x is 3 %, between x and y is 3 %, between y and z is 3 %, then what is the percentage recombination between b and y?
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DIFFERENTIAL EQUATIONS - EXAMPLE 20.1 : By using Excel program either on laptop or desktop PC, solve the differential equation dy / dx = -2y + x + 4 with h = 0.005, initial values : x = 0, y = 1. The 4th order Runge-Kutta method provides : y(N + 1) = y(N) + (1/6) (k1 + 2k2 +2k3 + k4), k1 = h [ -2y(N) + x(N) + 4 ], k2 = h { -2 [ y(N) + k1 / 2 ] + x(N) + h / 2 + 4 }, k3 = h { -2 [ y(N) + k2 / 2 ] + x(N) + h / 2 + 4 }, k4 = h { -2 [ y(N) + k3 ] + x(N) + h + 4 }. What is the value of y at x = 0.5?
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ENGINEERING MATHEMATICS - EXAMPLE 8.1 : A local utility burns coal having the following composition on a dry basis : Carbon (C) 83.05 %, hydrogen (H) 4.45 %, oxygen (O) 3.36 %, nitrogen (N) 1.08 %, sulfur (S) 0.7 % and ash 7.36 %. Calculate the ash free composition of the coal with reference to C, H, O, N and S.
BIOCHEMICAL ENGINEERING INSTRUMENTATION - EXAMPLE 29.2 : (a) In order to determine the slurry volume (L) in chromatography, arrange the formula using the following parameters : slurry concentration (%), slurry volume (L), settled chromatography medium volume (L), 100. (b) In order to determine the chromatography medium volume (L) in gel filtration chromatography, arrange the formula using the following parameters : sample volume to be processed (L), chromatography medium volume (L), sample volume in percent of total column volume (%), 100.
QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.3 : In photoelectrical effect analysis of quantum chemistry, let E = kinetic energy of electron, p = intensity of UV light, f = frequency of UV light. According to Classical Theory, E = c for all values of f, E = mp. According to Quantum Theory, E = c for all values of p, E = mf + c. In a graph, m and c are constants where m is slope and c is y intercept. If m = 2 and c = 3 with similar value of E : (a) find the value of p according to Classical Theory; (b) find the value of f according to Quantum Theory.
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