REACTION ENGINEERING - EXAMPLE 13.3 : The half-life for first order reaction could be described in the differential equation dC / dt = -kC where k is a constant, C is concentration and t is time. (a) Find the equation of C as a function of t. (b) Find the half life for such reaction or the time required to reduce 50 % of the initial concentration, where k = 0.139 per minute. (c) When the initial concentration Co is 16 mol / cubic metre, how long does the reaction required to achieve the final concentration of 1 mol / cubic metre?
REACTION ENGINEERING - ANSWER 13.3 : (a) dC / dt = -kC, dC / C = -k dt. Integrate both sides gives ln C - ln Co = ln (C / Co) = -kt, C = Co exp (-kt). (b) When C / Co = 0.5, t = [ ln (C / Co) ] / (-k) = [ ln (0.5) ] / (-0.139) = 4.9867 minutes. (c) Step 1 : 16 to 8 mol per cubic metre. Step 2 : 8 to 4. Step 3 : 4 to 2. Step 4 : 2 to 1. Each step takes t minutes. There are 4 steps needed from 16 to 1 mol / cubic metre or 4t = 19.9468 minutes. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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Chemical Engineering Energy Balance - Please match the term A - E as follow with the stated definition : A. Yield. B. Selectivity. C. Relative saturation. D. Molal saturation. E. Absolute saturation. i. Answer : ? (moles of desired product formed) / (moles that would have been formed if there were no side reactions and the limiting reactant has reacted completely). ii. Answer : ? (moles of desired product formed) / (moles of undesired product formed). iii. Answer : ? (relative humidity 40 % means partial pressure of water vapour equals 4 / 10 of the vapour pressure of water at the system temperature). iv. Answer : ? (moles of vapour) / (moles of vapour dry gas). v. Answer : ? (mass of vapour) / (mass of dry gas).
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Question 89 - A hemocytometer is a device that is used for counting cells. In an engineering experiment, 100 microlitres of cell suspension is diluted with 50 microlitres of Trypan blue dye. Only death cells appear blue in color when stained with the dye. There are 57 cells detected in a hemocytometer, where 5.3 % of them appear blue when the chamber of the meter is placed under a microscope. Each square of a chamber can contain 0.0001 mL of liquid. (a) Calculate the number of viable cells. (b) The cells ocupied 5 squares. Calculate the average number of viable cells / square. (c) Calculate the dilution factor of the cell suspension by using the formula : Dilution = final volume / initial volume. (d) Calculate the concentration of viable cells / mL by using the formula : Concentration = (Average number of viable cells / square) x dilution x (square / volume).
ACCOUNTING AND FINANCIAL ENGINEERING - EXAMPLE 34.36 : Du Pont analysis is used to perform calculation on Return On Equity (ROE) for an engineering organization. Let Net Income = A; Earning Before Tax (EBT) = B; Earning Before Interest, Tax (EBIT) = C; Sales = D; Assets = E; Equity = F. In 5-step Du Pont formula, let Tax Burden = G = A / B; Interest Burden = H = B / C = 1.04; EBIT % = I = C / D = 0.27; Asset Turnover = J = D / E = 0.66; Leverage = K = E / F = 2.66; ROE = L = A / F. If (1 / G) = (4 / 3) : (a) find the value of L; (b) calculate the values of A, B, C, E and F when D = $1500; (c) verify the answer (b) is correct by using the answer (a).
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