What is gibbs free energy?
Answer / Dharmendra Singh Rathor
Gibbs Free Energy (G) is a thermodynamic quantity that gives the maximum reversible work that can be done by a system at constant temperature and pressure. It is a measure of the total energy available to do useful work in a chemical reaction.
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Water flows through a pipe with circular cross sectional area at the rate of V / t = 80 L / s where V is the volume and t is time. Let Av = 80 L / s where A is cross sectional area and v is velocity of fluid. For point 1, the radius of the pipe is 16 cm. For point 2, the radius of the pipe is 8 cm. Find (a) the velocity at point 1; (b) the velocity at point 2; (c) the pressure at point 2 by using Bernoulli’s equation where P Rgy 0.5 RV = constant. P is the pressure, R = density of fluid, V = square of fluid’s velocity, g = gravitational constant of 9.81 N / kg and y = 2 m = difference of height at 2 points. The pressure of point 1 is 180 kPa.
What is the difference between cfm (cubic feet per minute) and scfm (standard cubic feet per minute)?
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CHEMICAL ENERGY BALANCE - EXAMPLE 11.5 : According to Margules Equation, P = x(1) p(1) g(1) + x(2) p(2) g(2) for a two-component mixture where P is bubble pressure, x is mole fraction, p is saturation pressure, g is constant given by ln g(1) = x(2) A x(2). Find the value of A as a constant when P = 1.08 bar, p(1) = 0.82 bar, p(2) = 1.93 bar in a 50 : 50 mole fraction mixture. Estimate the pressure required to completely liquefy the 30 : 70 mixture using the same equation, by proving P = 1.39 bar. Take note that ln g(2) = x(1) A x(1), ln g(1) = x(2) A x(2).
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Question - Chemical Engineering Material - In crystal material, hexagonal crystal system could form 4-digit index in certain direction of solid. For [1(-1)0] direction in the hexagonal crystal systems of particular catalyst applied in fume removal of incinerator, what is the four-digit index for this direction? Hint : The transformation equations between the 3-digit [h’k’l’] and the 4-digit [hkil] indices are : h = (1/3) (2h’ – k’); i = - (h + k); k = (1/3) (2k’ – h’); l = l’. A. [(-1)100] B. [1(-1)00] C. [(-1)000] D. [00(-1)(-1)] E. [(-1)0(-1)0]
What is gibbs free energy?
Question 35 – A mixture consists of benzene (B), toluene (T) and xylene (X). At a temperature of 353 K, the data of vapor pressures : B : 754.12, T : 289.71, X : 91.19. Unit is mm Hg. The pressure P is 0.5 atm. The value of k for each substance is k = (vapor pressure) / P. (a) Calculate k for B, T and X. Let L / V = 0.65. (b) By using the equation V = F / [ (L / V) + 1 ], find the value of V when F = 100, then what is the value of L?
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FOOD ENGINEERING - QUESTION 23.3 : (a) In the measurement of the browning (optical density) of fruit juice at 10 day interval, the following pairs of data are obtained with time t in days and browning or optical density (OD) : t = 0, OD = 0.05; t = 10, OD = 0.071; t = 20, OD = 0.089; t = 30, OD = 0.11; t = 40, OD = 0.128; t = 50, OD = 0.149; t = 60, OD = 0.17. (i) By using Excel or other programs, determine if such browning reaction can be characterised by pseudo zero order kinetics, with strong correlations between the data pairs of t and OD. (ii) When OD = 0.24, the shelf life T of such juice is expired. Calculate the value of T. (b) Let food cost percentage = ( food cost / food sales ) x 100. If total food cost of bread and butter are $25, food cost percentage of bread is 50 % and for butter is 50 %, find the total food sales of bread and butter.
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