CHEMICAL MATERIAL BALANCE - EXAMPLE 2.1 : Two methanol-water mixtures are contained in separate tanks. The first mixture contains 40.0 wt % methanol and the second contains 70.0 wt % methanol. If 200 kg of the first mixture is combined with 150 kg of the second, what are the mass and composition of the product? The symbol of weight percent is wt %.
CHEMICAL MATERIAL BALANCE - ANSWER 2.1 : Total mass of product mixture = 200 kg + 150 kg = 350 kg. Total mass of methanol in product mixture = 0.4 x 200 + 0.7 x 150 = 80 kg + 105 kg = 185 kg. Mass fraction of methanol in product mixture = 185 / 350 = 0.5286 or 52.86 wt %. Mass fraction of water in product mixture = 1 - 0.5286 = 0.4714 or 47.14 wt %. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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Question 51 - A batch reactor is designed for the system of the irreversible, elementary liquid-phase hydration of butylene oxide that produces butylene glycol. At the reaction temperature T = 323 K, the reaction rate constant is k = 0.00083 L / (mol - min). The initial concentration of butylene oxide is 0.25 mol / L = Ca. The reaction is conducted using water as the solvent, so that water is in large excess. (a) Let the molecular weight of water is 18 g / mol and the mass of 1 kg in 1 L of water, calculate the molar density of water, Cb in the unit of mol / L. (b) Determine the final conversion, X of butylene oxide in the batch reactor after t = 45 min of reaction time. Use the formula X = 1 - 1 / exp [ kt (Cb) ] derived from material balance. (c) Find the equation of t as a function of X.
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