Answer / kangchuentat

CHEMICAL ENERGY BALANCE - ANSWER 11.4 : By trial and error, T = 84.37 degree Celsius. Excel program may be used, either by Solver or Goal Seek. Overall equation : y(1) + y(2) = 1 = { 0.4 exp [ 14.3 - 2945 / (T + 224) ] + 0.6 exp [ 14.2 - 2943 / (T + 209) ] } / 85. Solve the equation by computer iteration with one unknown will produce T = 84.37 degree Celsius. Let x(2) = 1 - x(1) = 1 - 0.4 = 0.6, P = 85. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.

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CHEMICAL ENERGY BALANCE - EXAMPLE 11.5 : According to Margules Equation, P = x(1) p(1) g(1) + x(2) p(2) g(2) for a two-component mixture where P is bubble pressure, x is mole fraction, p is saturation pressure, g is constant given by ln g(1) = x(2) A x(2). Find the value of A as a constant when P = 1.08 bar, p(1) = 0.82 bar, p(2) = 1.93 bar in a 50 : 50 mole fraction mixture. Estimate the pressure required to completely liquefy the 30 : 70 mixture using the same equation, by proving P = 1.39 bar. Take note that ln g(2) = x(1) A x(1), ln g(1) = x(2) A x(2).

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