Question 56 - The kinetic behavior of an enzyme could be described using Michalis - Menten equation : Vo = Vmax [S] / (Km + [S]). Derive this equation from [ES] = [E]total [S] / (Km + [S]), Vmax = Kcat [E]total, Vo = Kcat [ES].
Answer / kang chuen tat (malaysia - pen
Answer 56 - Vo = Kcat [ES] = Kcat [E]total [S] / (Km + [S]) where [ES] = [E]total [S] / (Km + [S]). When Vmax = Kcat [E]total, Vo = Kcat [E]total [S] / (Km + [S]) = Vmax [S] /(Km + [S]) (Derived). The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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Question 31 – For liquid benzene, the CP constants are : a = 129440, b = - 169.5, c = 0.64781. Reference temperature is 298 K. The temperature of benzene is 60 degree Celsius. Calculate the enthalpy of benzene by using the formula H = a (DT) + (b/2) (T^2 – TREF^2) + (c/3) (T^3 – TREF^3) where ^ is power, DT is temperature difference with TREF = 298 K. H is in J / kmol. DT = T – TREF.
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QUANTUM COMPUTING - EXAMPLE 32.4 : A system of linear congruences consists of 3 equations : X ≡ 1 (mod 2), X ≡ 3 (mod 3), X ≡ 4 (mod 5). X has positive values. (a)(i) List the values of these equations from 1 to approximately 40. (ii) Find the first smallest value and second smallest value of X. (iii) Guess the third smallest value of X. (b) Let X ≡ Aa (mod Ma), X ≡ Ab (mod Mb), X ≡ Ac (mod Mc). According to Chinese remainder theorem, X ≡ (Aa x Ya x Md + Ab x Yb x Me + Ac x Yc x Mf) [ mod (Ma x Mb x Mc) ]. (i) Show that Ma, Mb and Mc have the greatest common divisor of Ma x Mb x Mc. (ii) Find the values of Md, Me and Mf if Md = Mb x Mc, Me = Ma x Mc and Mf = Ma x Mb. (iii) Find the values of Ya, Yb and Yc if Ya = Remainder of (Md / Ma), Yb = Remainder of (Me / Mb) and Yc = Remainder of (Mf / Mc). (iv) Use Chinese remainder theorem to find X.
QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.9 : When an algebraic product is defined on the space, the Lie bracket is the commutator [x,y] = xy - yx according to Lie algebra in mathematics. If [p,x] f(x) = px f(x) - xp f(x), p = -ih d / dx, find the value of [p,x] in term of i and h.
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Question 99 - (a) The quantum number m is given by m = -s, -s + 1. If s = 0.5, find the values of m. (b) | T > = (cos T) | V > + (sin T) | H >. The V and H states form a basis for all polarizations. Let cos T = 0.8. (i) If (sin T)(sin T) + (cos T)(cos T) = 1, find the value of sin T. (ii) For | T > = a | V > + b | H >, where a x a represents the probability of | V > and b x b represents the probability of | H >. Which one is more abundant, | V > or | H >? (iii) Find the value of T without using any mathematical tools.
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According to Shockley equation, the I – V characteristic of a diode is approximated by I = IS [ exp (nVD / VT) – 1 ]. For silicon, let the reverse bias saturation current IS as 0.000000000001. If n is ideality factor with value of 1.5, VT as thermal voltage drop of 0.026 V at room temperature, what is the value of current I that passes through the silicon diode in the heater of evaporator when the forward voltage drop VD = 0.026 V? Please take note that exp is the exponential function with e(1) = 2.718, e(2) = 7.389.
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