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Question 51 - A batch reactor is designed for the system of the irreversible, elementary liquid-phase hydration of butylene oxide that produces butylene glycol. At the reaction temperature T = 323 K, the reaction rate constant is k = 0.00083 L / (mol - min). The initial concentration of butylene oxide is 0.25 mol / L = Ca. The reaction is conducted using water as the solvent, so that water is in large excess. (a) Let the molecular weight of water is 18 g / mol and the mass of 1 kg in 1 L of water, calculate the molar density of water, Cb in the unit of mol / L. (b) Determine the final conversion, X of butylene oxide in the batch reactor after t = 45 min of reaction time. Use the formula X = 1 - 1 / exp [ kt (Cb) ] derived from material balance. (c) Find the equation of t as a function of X.

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FOOD ENGINEERING - QUESTION 23.2 : (a) A dryer reduces the moisture content of 100 kg of a potato product from 80 % to 10 % moisture. Find the mass of the water removed in such drying process. (b) During the drying process, the air is cooled from 80 °C to 71 °C in passing through the dryer. If the latent heat of vaporization corresponding to a saturation temperature of 71 °C is 2331 kJ / kg for water, find the heat energy required to evaporate the water only. (c) Assume potato enters at 24 °C, which is also the ambient air temperature, and leaves at the same temperature as the exit air. The specific heat of potato is 3.43 kJ / (kg °C). Find the minimum heat energy required to raise the temperature of the potatoes. (d) 250 kg of steam at 70 kPa gauge is used to heat 49,800 cubic metre of air to 80 °C, and the air is cooled to 71 °C in passing through the dryer. If the latent heat of steam at 70 kPa gauge is 2283 kJ / kg, find the heat energy in steam. (e) Calculate the efficiency of the dryer based heat input and output, in drying air. Use the formula (Ti - To) / (Ti - Ta) where Ti is the inlet (high) air temperature into the dryer, To is the outlet air temperature from the dryer, and Ta is the ambient air temperature.

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QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.5 : In a wavefunction, let P(x) = A cos kx + B sin kx. By using the boundary conditions of x = 0 and x = l, where P(0) = P(l) = 0, prove by mathematical calculation that P(x) = B sin (npx / l) where p = 22 / 7 approximately, n is a rounded number. A, B and k are constants.

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