CHEMICAL ENERGY BALANCE - EXAMPLE 11.5 : According to Margules Equation, P = x(1) p(1) g(1) + x(2) p(2) g(2) for a two-component mixture where P is bubble pressure, x is mole fraction, p is saturation pressure, g is constant given by ln g(1) = x(2) A x(2). Find the value of A as a constant when P = 1.08 bar, p(1) = 0.82 bar, p(2) = 1.93 bar in a 50 : 50 mole fraction mixture. Estimate the pressure required to completely liquefy the 30 : 70 mixture using the same equation, by proving P = 1.39 bar. Take note that ln g(2) = x(1) A x(1), ln g(1) = x(2) A x(2).
CHEMICAL ENERGY BALANCE - ANSWER 11.5 : Let x(1) = x(2) = 0.5 for 50 : 50 mole fraction mixture, then P = x(1) p(1) g(1) + x(2) p(2) g(2) or 1.08 = 0.5 (0.82) exp [ (0.5) A (0.5) ] + 0.5 (1.93) exp [ (0.5) A (0.5) ]. Then exp [ (0.5) A (0.5) ] = 1.08 / [ 0.5 (0.82 + 1.93) ] = 0.785, A = - 0.97. P for 30 : 70 mixture is P = x(1) p(1) g(1) + x(2) p(2) g(2) = (0.3) (0.82) exp [ (-0.97) (0.7) (0.7) ] + (0.7) (1.93) exp [ (-0.97) (0.3) (0.3) ] = 1.39 bar (proven) where g(1) = exp [ A x(2) x(2) ], g(2) = exp [ A x(1) x(1) ]. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
Is This Answer Correct ? | 0 Yes | 0 No |
Why are decomposition reactions called the opposite of combination reactions?
oil field interview question
What is an effective means of removing silicon from aluminum?
Explain various protein purification techniques?
Suppose you have hot oil and cold water, what kind fluid you flow In shell side and tube side and why?
What is are the main terms in Unit Operations? and what is its charecteristics?
Mention some of the specialized grinding and crushing methods.
Explain what are some good uses of low-grade steam at 12 atm and 1920c?
Name some common causes of control valve noise?
Hi.. Me going to tke test for management trainee(technical) Post I am an chemical engineering student . Can u guide how to prepare for this test.Can u send me test paper pattern..?
what is the various utilities of the process plant?
REACTION ENGINEERING - EXAMPLE 13.3 : The half-life for first order reaction could be described in the differential equation dC / dt = -kC where k is a constant, C is concentration and t is time. (a) Find the equation of C as a function of t. (b) Find the half life for such reaction or the time required to reduce 50 % of the initial concentration, where k = 0.139 per minute. (c) When the initial concentration Co is 16 mol / cubic metre, how long does the reaction required to achieve the final concentration of 1 mol / cubic metre?