Question 93 - In thin layer chromatography (TLC), let retention factor Rf = (distance traveled by solute) / (distance traveled by solvent). Silica gel is used as stationary phase which is more polar than the hexane solvent as mobile phase. If the Rf values of 3 solutes A, B and C are 1.5, 0.75 and 1 respectively, compare the polarities of A, B and C with reasons.
Polarities : A < C < B. A is least polar since it travels farthest with the mobile phase, whereas B is most polar as it is attracted to the stationary phase and travels least. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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ENGINEERING MATHEMATICS - EXAMPLE 8.4 : Let 1 ^ 1 = 1, 2 ^ 2 = 4, 3 ^ 3 = 27. By using the Excel computer programming - either by Solver or Goal Seek, find the value of v for the Van der Waals equation (P - a / v ^2) (v - b) = RT where a = 18.82, b = 0.1193, P = 2, R = 0.082, T = 5000 for benzene. Describe briefly how to use Solver and Goal Seek in Excel program of computer to find the solution quickly.
BIOCHEMICAL ENGINEERING INSTRUMENTATION - EXAMPLE 29.3 : In thin layer chromatography (TLC), let retention factor Rf = (distance traveled by solute) / (distance traveled by solvent). Silica gel is used as stationary phase which is more polar than the hexane solvent as mobile phase. If the Rf values of 3 solutes A, B and C are 1.5, 0.75 and 1 respectively, compare the polarities of A, B and C with reasons.
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Question 72 - (a) According to United States Department of Agriculture (USDA) (http://ndb.nal.usda.gov/ndb/search/list, accessed 12 August 2016), 100 g of potatoes generate 77 kcal of energy. For raw tomatoes, 111 g have 18 kcal of energy. Question : How much energy will one gain if 150 g of heated potatoes are eaten with 200 g of raw tomatoes? (b) If 1 Calorie = 1 food Calorie = 1 kilocalorie and 1000 calories = 1 food Calorie, then how many Calories are there in 9600 calories? (c) According to a food package of potato chips, 210 Calories are produced per serving size of 34 g. In actual experiment of food calorimetry lab, 1.75 g of potato chips, when burnt, will produce 9.6 Calories. For each serving size of potato chip, find the difference of Calories between the actual experimental value and the value stated on the food package. (d) The specific heat of water is c = 1 cal / (g.K) where cal is calory, g is gram and K is Kelvin. Then what is the temperature rise of water, in degree Celsius, when 150 g of water is heated by 9600 calories of burning food?
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