Hi, I am preparing for Indian Forest Service (UPSC). Can
you please help me to get previous years question papers
(Chemcial Engineerign) (atleast 5).
Answer / keshav
you can download them from
http://examrace.com/IFSpreviousyrpapers.aspx
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CHEMICAL ENERGY BALANCE - EXAMPLE 11.5 : According to Margules Equation, P = x(1) p(1) g(1) + x(2) p(2) g(2) for a two-component mixture where P is bubble pressure, x is mole fraction, p is saturation pressure, g is constant given by ln g(1) = x(2) A x(2). Find the value of A as a constant when P = 1.08 bar, p(1) = 0.82 bar, p(2) = 1.93 bar in a 50 : 50 mole fraction mixture. Estimate the pressure required to completely liquefy the 30 : 70 mixture using the same equation, by proving P = 1.39 bar. Take note that ln g(2) = x(1) A x(1), ln g(1) = x(2) A x(2).
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HEAT TRANSFER - EXAMPLE 5.3 : In a cylinder with a hollow, let a is outside radius and b is the inside radius. In a steady state temperature distribution with no heat generation, the differential equation is (d / dr) (r dT / dr) = 0 where r is for radius and T is for temperature. (a) Integrate the heat equation above into T(r) in term of r. (b) At r = a, T = c; at r = b, T = d. Find the heat equation of T(r) in term of r, a, b, c, d.
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Question 75 - The molecular weights M in kg / mol of 3 different monomers a, b and c in a polymer are Ma = 14, Mb = 16 and Mc = 18. The fraction of polymer chain X of 3 different monomers a, b and c in a polymer are Xa = 0.5, Xb = 0.3 and Xc = 0.2. (i) Calculate number average molecular weight by using the formula Ma Xa + Mb Xb + Mc Xc. (ii) Calculate weight average molecular weight by using the formula (Ma Xa Ma + Mb Xb Mb + Mc Xc Mc) / (Ma Xa + Mb Xb + Mc Xc). (iii) Calculate the polydispersity by using the answer in (ii) divided by answer in (i). (iv) If the molecular weight of repeat unit is 12, calculate the degree of polymerization by using the formula (Ma Xa + Mb Xb + Mc Xc) / (molecular weight of repeat unit).
BIOCHEMICAL ENGINEERING INSTRUMENTATION - EXAMPLE 29.3 : In thin layer chromatography (TLC), let retention factor Rf = (distance traveled by solute) / (distance traveled by solvent). Silica gel is used as stationary phase which is more polar than the hexane solvent as mobile phase. If the Rf values of 3 solutes A, B and C are 1.5, 0.75 and 1 respectively, compare the polarities of A, B and C with reasons.