how to pd(2) to pd(0) in suzuki reaction
Answers were Sorted based on User's Feedback
Answer / gangaraju.pj
when palladium diphenyl phosphine complex with aryl halide
it goes to pd(2) from pd(o) this is called oxidative
addition. again it goes to pd(0) stage after metal
transformation followed by reductive elimination.
| Is This Answer Correct ? | 8 Yes | 0 No |
Answer / sunil
pph3 is a neutral ligand..so its oxdation state should be 0...and the overall complex oxdation state will be changed to pd(2) when it reacts with aryl halide substitution
| Is This Answer Correct ? | 3 Yes | 0 No |
Answer / pushpal bhaket
In the Suzuki reaction. The first step is the oxidative
addition. In this step, the Palladium need to be zero
valency state. In case of Pd(PPh3)4, the palladium metal is
in zero valency and therefore can easily take part in the
oxidative addition. However, for other Palladium (II)
complexes eg Pd(OAc)2, Pd(PPh3)2Cl2, Pd2
(MeCN)2Cl2 reducers (for instance Et3N) are added which
converts Pd(II) to Pd(0).
| Is This Answer Correct ? | 3 Yes | 1 No |
Answer / 15-11-08
when palladium diphenyl phosphine complex with aryl halide
it goes to pd(2) from pd(o) this is called oxidative
addition. again it goes to pd(0) stage after metal
transformation followed by reductive elimination.
| Is This Answer Correct ? | 2 Yes | 1 No |
Actinium-227 has a long half-life and emits alpha particles. How can this property be harnessed in radiation detectors or other monitoring devices?
Which organic compound is used as a fuel in jet air crafts?
Is LOD and LOQ values differ for different substrat (eg milk, tissue, egg etc.) for same compound (eg pesticide flumethrin)in same instrument(eg GC)?
Suppose we prepared pH buffer solution in lab.and calibrate against NIST solution, and same shall going to used upto 30 days. is it possible to stable pH and appearance? suggest?
uv,ri,pda detactor principles ?
1 Answers Aurobindo, Mankind, ZCL Chemicals,
Arrange the following in their increasing polarity order Carboxylic acid, hydroxyl, phenyl, amino and aldehyde
why antharacene use hplc calibration
which functional groups are present in cortisone?
what is functionality of polymer? how can we get theoretical and practically?
0 Answers Atul, Domax, Mohrish Pharmaceuticals,
How to interlude aldehyde group in aromatic compound
Actinium has potential applications in cancer treatment. Could you elaborate on how Actinium-225 is used in targeted alpha-particle cancer therapy?
naphtha and hexane mixture can be used a fuel or not