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What is the role of SO2,I2, Methanolic hydroxide and any
base in Karlficher titration

Answers were Sorted based on User's Feedback



What is the role of SO2,I2, Methanolic hydroxide and any base in Karlficher titration..

Answer / himal patel

meoH use as a media,when S02+water+MeOH,and base react it
give intermediatealkyl sulphite salt which is oxydised by I2
and give alkyl sulphate in this oxydation reaction water
consume.and water is consume is (1:1) of I2,when all water
consume Excess amount ofI2 detect voltemetrycally by refrence
electrode<and water amount is calculated by consumption of KF
reagent

Is This Answer Correct ?    14 Yes 0 No

What is the role of SO2,I2, Methanolic hydroxide and any base in Karlficher titration..

Answer / pharmainterview

I2 reacts with water.
CH3OH maintain the stoichiometry of rection
SO2 balancing the reaction.
BASE maitains the pH of reaction.

Regards
http://www.pharmainterviewquestions.blogspot.in/

Is This Answer Correct ?    5 Yes 0 No

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